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Yes it is safe to use vinegar on your car. A couple of months ago I had some deposits form on my vehicle. It looked like someone had poured concrete onto the paint and NOTHING would take it out. I read about apple vinegar and tried it straight out of the bottle. First I placed some napkins where the issue was and then just poured the vinegar and let it sit until it rubbed off without any difficulty. The paint is still looking great.
It will remove any wax that you had on your car. You'll def have to rewax after you use the vinegar.
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